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Yes, both Pleo and Bill.com offer a Free Trial.
Pleo is designed for Large Enterprises, Medium Business and Small Business.
Bill.com is designed for Freelancers, Large Enterprises, Medium Business and Small Business.
Pricing for Pleo Starts at $50/month when yearly whereas for Bill.com Starts at $0/user/month.
Some top alternatives to Pleo includes and Bill.com.
Some top alternatives to Bill.com includes Xero, Sage Accounting (Sage One), Patriot Accounting, AvidXchange, APXPRESS, Paypool, Melio, QuickFile, InvoiceWorks, Tipalti, Stampli and Enverus OpenInvoice.