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Yes, both Xero and Bill.com offer a Free Trial.
Xero is designed for Freelancers, Medium Business and Small Business.
Bill.com is designed for Freelancers, Large Enterprises, Medium Business and Small Business.
The starting price of Bill.com begins at $0/user/month, while pricing details for Xero are unavailable.
Some top alternatives to Xero includes Patriot Accounting, Quickbooks, Sage Accounting (Sage One), Zoho Books, Zoho Daybook, QuickFile, Sage Business Cloud Accounting, MYOB, QuickBooks Desktop Pro, QuickBooks Online Advanced and Sage 50cloud Accounting.
Some top alternatives to Bill.com includes Xero, Patriot Accounting, AvidXchange, APXPRESS, Paypool, Melio, QuickFile, InvoiceWorks, Tipalti, Stampli and Enverus OpenInvoice.